建筑物掏土纠倾法单孔与多孔塑性区特性研究及工程应用

在建筑物水平掏土纠倾工程中，掏土孔间距是影响纠倾工程安全与工期的重要因素。为了快速准确地确定纠倾工程中的水平掏土孔间距，研究了单个掏土孔和多个掏土孔情况下孔周边土体塑性区发展特性。利用土体塑性力学分析计算得到了单孔下的孔周土塑性区半径，而后通过有限元模拟得到孔周土体塑性区半径的数值解，将孔周塑性区半径解析解与数值解进行了对比。并通过有限元数值模型研究了多个掏土孔相互影响情况下的塑性区发展规律，以孔间土体塑性区贯通时的距离作为掏土孔间距。考虑土体参数随机特性的影响，研究不同上部荷载作用下掏土孔间距的取值变化规律，上部面荷载与地基承载力特征值比值用p表示，孔间距与掏土孔直径比值用n表示。研究发现：多孔塑性区半径（孔间塑性区贯通时）是单孔塑性区半径的1.3倍左右;标准化荷载p与孔间距比值n二者呈线性关系;通过不同土体参数及上部荷载的不同情况下的p-n曲线，给出了掏土孔间距建议值。同时，将研究结果与三个实际工程进行对比，发现p-n曲线法与实际结果更为接近。     

Simulation and energy optimization of the stabilizer tower of a pyrolysis gasoline hydrogenation unit

Energy optimization of second distillation tower of a pyrolysis gasoline hydrogenation unit has been studied by the thermal cycle of vapor recompression method. The mentioned cycle is connected to the second distillation tower of the stabilizer of pyrolysis gasoline, and the results are found promising. The composite pinch curve for both the current and the optimized methods are shown. Moreover, an increase in the heat transfer rate in heat exchanger E-1014 causes energy recovery in reboiler. According to simulation results, by vapor recompression to 1970 kPa and using this heat source for thermal integration, condenser and reboiler’s energies are decreased by 56.93 and 30.4 percentage, respectively.     

30CrNi3MoV钢的热变形行为及热加工图

采用Gleeble-3500热模拟试验机对30CrNi3MoV钢进行单向热压缩试验,研究了其在变形温度950~1150 ℃、应变速率0.01~10 s^-1的热变形行为,构建了应变补偿型流变应力本构方程,并绘制出该钢的热加工图。结果表明,30CrNi3MoV钢真应力-真应变曲线有3种不同特征:高温小应变速率时,表现为典型的动态再结晶过程;低温小应变速率时,曲线为动态回复特征;应变速率较大时,应力随应变的增大而增大,无明显的峰值应力。采用5次多项式拟合构建的应变耦合流变应力本构方程具有高的精确度,采用该方程获得的预测值与试验值的平均相对误差为3.2%,相关性系数R值为0.993。从热加工图中得到试验钢最佳的热加工工艺参数范围是:变形温度为1020~1150 ℃、应变速率为0.03~0.35 s^-1。     

井下安全阀力学性能分析

井下安全阀对安全性和可靠性要求较高。以渤海油田常用油管携带式井下安全阀为分析对象,对其工作压力、地面控制压力、全开启和全关闭压力、最大下入深度和自平衡能力等关键力学性能进行分析。井下安全阀的工作压力值与地面液控压力值相等,其选取依据为井口压力; 全开启和全关闭液控压力值可通过压力曲线法得到; 最大下入深度取决于弹簧安装时的预紧力; 自平衡能力与活塞面积和自平衡孔面积的比值有关,比值越大,自平衡能力越强。     

重水浓度与吸光度关系曲线类型研究

重水作为反应堆的慢化材料，其浓度直接影响反应堆的安全和性能。为研究其重水浓度与吸光度间的关系曲线类型，基于朗伯-比尔定律，从理论上推导出液态重水中某种水分子的红外吸收峰分别与0~2种其他水分子的红外吸收峰发生重叠时重水浓度与吸光度间的关系式，分情况对二者之间的关系曲线类型进行讨论。采用傅里叶变换红外光谱仪，测得浓度为0.015%~99.98%（摩尔比）的重水标准样品吸收光谱，对重水浓度和吸光度间的关系曲线类型进行验证，理论推导与实际吻合。研究表明，一般情况下，宽浓度范围内，重水浓度与吸光度间的关系曲线类型为二次曲线；窄浓度范围内，关系曲线类型为线性。特殊情况下，吸光度为定值或关系曲线类型为线性。     

Discharge coefficient for vertical sluice gate under submerged condition using contraction and energy loss coefficients

A novel method is suggested for the determination of flow discharge in vertical sluice gates with considerably small bias. First, in order to derive an equation for the discharge coefficient, energy-momentum equations are implemented to define the physical realization of the phenomenon. Afterward, the discharge coefficient is presented in terms of contraction and energy loss coefficients. Subsequently, discharge coefficient, contraction, and energy loss coefficients were determined through an implicit optimization technique on the data. Data analysis illustrated that there is a meaningful power relationship between the contraction and energy loss coefficients. Thereafter, dimensional analysis is performed and an explicit best-fit regression equation is developed for defining the energy loss coefficient. The obtained equations for contraction and energy loss coefficients were then used in the computation of the discharge coefficient and determination of the flow discharge in the vertical sluice gate. The performance of the developed approach is validated against the selected benchmarks existing in the literature.     

Charge Transportation and Chirality in Liquid Crystalline Helical Network Phases of Achiral BTBT-Derived Polycatenar Molecules

First examples of multichain (polycatenar) compounds, based on the π-conjugated [1]benzothieno[3,2-b]benzothiophene unit are designed, synthesized, and their soft self-assembly and charge carrier mobility are investigated. These compounds, terminated by the new fan-shaped 2-brominated 3,4,5-trialkoxybenzoate moiety, form bicontinuous cubic liquid crystalline (LC) phases with helical network structure over extremely wide temperature ranges (>200 K), including ambient temperature. Compounds with short chains show an achiral cubic phase with the double network, which upon increasing the chain length, is at first replaced by a tetragonal 3D phase and then by a mirror symmetry is broken triple network cubic phase. In the networks, the capability of bypassing defects provides enhanced charge carrier mobility compared to imperfectly aligned columnar phases, and the charge transportation is non-dispersive, as only rarely observed for LC materials. At the transition to a semicrystalline helical network phase, the conductivity is further enhanced by almost one order of magnitude. In addition, a mirror symmetry broken isotropic liquid phase is formed beside the 3D phases, which upon chain elongation is removed and replaced by a hexagonal columnar LC phase.